Effect of Copper Doping on Charge Ordering in La 1/3 Ca 2/3 Mn 1 - y Cu y O 3 (0 ≤ y ≤ 0.07)

Abstract

Electron microscope studies have shown that the presence of copper suppresses the formation of a regular superstructure, which is characteristic of the undoped starting compound, beginning already from low concentrations (y=0.01). Differential scanning calorimetry revealed a substantial decrease in the transition entropy at the onset of charge ordering in copper-doped samples as compared to the starting compound. Doping with copper destroys long-range charge-orbital ordering and retains apparently only short-range order